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Diphenylprolinol silyl ether was found to be an effective organocatalyst in the enantioselective and direct Michael reaction of nitroethanol and α,β-unsaturated aldehydes, affording the 1-hydroxy-trans-3,4-disubstituted tetrahydropyrans after isomerization. The generated Michael addition products are useful synthetic intermediates, which can be …Professor Li-Huei Tsai is the Director of the Picower Institute for Learning and Memory at the Massachusetts Institute of Technology, a Picower Professor of Neuroscience, and an Associate Member of the Broad Institute. She obtained her Ph.D. from the University of Texas Southwestern Medical Center in Dallas and completed her postdoctoral ...Huicai Huang's 26 research works with 386 citations and 547 reads, including: Nickel-Catalyzed, Enantioselective Hydrofluoromethylation of Olefins: Access to Chiral α …Large batch size training in deep neural networks (DNNs) possesses a well-known 'generalization gap' that remarkably induces generalization performance degradation. However, it remains unclear how varying batch size affects the structure of a NN. Here, we combine theory with experiments to explore the evolution of the basic structural …

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